Chiral Pyridinyloxazolidine Ligands and Cuprous Chloride Complexes

Two chiral bidentate C1-symmetric oxazolidine ligands and coordination complexes with Cuprous Chloride(WSDTY)(Cu2Cl4(C15H14N2O)2 (3) and [Cu2Cl4(C16H16N2O)2]·CH3OH (4)) were synthesized and characterized by X-ray crystallographic techniques. The ligands maintain the same stereochemistry within all structures, resulting in an anti-relationship between the substituents. Structures and dimerized through bridging chlorides and has an extended hydrogen bonding network resulting in an infinite 1D chain.

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